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The Structures, Spectroscopic Properties, and Photodynamic Reactions of Three [RuCl(QN)NO]− Complexes (HQN = 8-Hydroxyquinoline and Its Derivatives) as Potential NO-Donating Drugs
المؤلفون المشاركون
Xie, Leilei
Liu, Lifang
Wang, Wenming
Ma, Zhiou
Xu, Liqun
Zhao, Xuan
Wang, Hongfei
المصدر
Bioinorganic Chemistry and Applications
العدد
المجلد 2018، العدد 2018 (31 ديسمبر/كانون الأول 2018)، ص ص. 1-9، 9ص.
الناشر
Hindawi Publishing Corporation
تاريخ النشر
2018-12-02
دولة النشر
مصر
عدد الصفحات
9
التخصصات الرئيسية
الملخص EN
The structures and spectral properties of three ruthenium complexes with 8-hydroxyquinoline (Hhqn) and their derivatives 2-methyl-8-quinolinoline (H2mqn) and 2-chloro-8-quiolinoline (H2cqn) as ligands (QN = hqn, 2mqn, or 2cqn) were calculated with density functional theory (DFT) at the B3LYP level.
The UV-Vis and IR spectra of the three [RuCl(QN)NO]− complexes were theoretically assigned via DFT calculations.
The calculated spectra reasonably correspond to the experimentally measured spectra.
Photoinduced NO release was confirmed through spin trapping of the electron paramagnetic resonance spectroscopy (EPR), and the dynamic process of the NO dissociation upon photoirradiation was monitored using time-resolved infrared (IR) spectroscopy.
Moreover, the energy levels and related components of frontier orbitals were further analyzed to understand the electronic effects of the substituent groups at the 2nd position of the ligands on their photochemical reactivity.
This study provides the basis for the design of NO donors with potential applications in photodynamic therapy.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
Xie, Leilei& Liu, Lifang& Ma, Zhiou& Xu, Liqun& Zhao, Xuan& Wang, Hongfei…[et al.]. 2018. The Structures, Spectroscopic Properties, and Photodynamic Reactions of Three [RuCl(QN)NO]− Complexes (HQN = 8-Hydroxyquinoline and Its Derivatives) as Potential NO-Donating Drugs. Bioinorganic Chemistry and Applications،Vol. 2018, no. 2018, pp.1-9.
https://search.emarefa.net/detail/BIM-1123184
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
Ma, Zhiou…[et al.]. The Structures, Spectroscopic Properties, and Photodynamic Reactions of Three [RuCl(QN)NO]− Complexes (HQN = 8-Hydroxyquinoline and Its Derivatives) as Potential NO-Donating Drugs. Bioinorganic Chemistry and Applications No. 2018 (2018), pp.1-9.
https://search.emarefa.net/detail/BIM-1123184
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
Xie, Leilei& Liu, Lifang& Ma, Zhiou& Xu, Liqun& Zhao, Xuan& Wang, Hongfei…[et al.]. The Structures, Spectroscopic Properties, and Photodynamic Reactions of Three [RuCl(QN)NO]− Complexes (HQN = 8-Hydroxyquinoline and Its Derivatives) as Potential NO-Donating Drugs. Bioinorganic Chemistry and Applications. 2018. Vol. 2018, no. 2018, pp.1-9.
https://search.emarefa.net/detail/BIM-1123184
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes bibliographical references
رقم السجل
BIM-1123184
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
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