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Ionothermal Synthesis of a Novel 3D Cobalt Coordination Polymer with a Uniquely Reported Framework: [BMI]2[Co2(BTC)2(H2O)2]
المؤلفون المشاركون
Ko, Il-Ju
Oh, Hyun-Chang
Cha, Yong-Jun
Han, Chae Hyeok
Choi, Eun-Young
المصدر
Advances in Materials Science and Engineering
العدد
المجلد 2017، العدد 2017 (31 ديسمبر/كانون الأول 2017)، ص ص. 1-6، 6ص.
الناشر
Hindawi Publishing Corporation
تاريخ النشر
2017-08-28
دولة النشر
مصر
عدد الصفحات
6
الملخص EN
The framework of [RMI]2[Co2(BTC)2(H2O)2] (RMI = 1-alkyl-3-methylimidazolium, alkyl; ethyl (EMI); propyl (PMI); butyl (BMI)), which has uniquely occurred in ionothermal reactions of metal salts and H3BTC (1,3,5-benzenetricarboxylic acid), an organic ligand, reappeared in this work.
Ionothermal reaction of cobalt acetate and H3BTC with [BMI]Br ionic liquid as the reaction medium yielded the novel coordination polymer [BMI]2[Co2(BTC)2(H2O)2] (compound B2).
Similar ionothermal reactions with different [EMI]Br and [PMI]Br as the reaction media have been previously reported to produce [EMI]2[Co3(BTC)2(OAc)2] (compound A1) and [PMI]2[Co2(BTC)2(H2O)2] (compound B1), respectively.
In contrast with the trinuclear secondary building unit of A1, the framework structure of B1 and B2 consists of dinuclear secondary building units in common, but with subtle distinction posed by the different size of the incorporated cations.
These structural differences amidst the frameworks showed interesting aspects, including guest and void volume, and were used to explain the chemical trend observed in the system.
Moreover, the physicochemical properties of the newly synthesized compound have been briefly discussed.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
Ko, Il-Ju& Oh, Hyun-Chang& Cha, Yong-Jun& Han, Chae Hyeok& Choi, Eun-Young. 2017. Ionothermal Synthesis of a Novel 3D Cobalt Coordination Polymer with a Uniquely Reported Framework: [BMI]2[Co2(BTC)2(H2O)2]. Advances in Materials Science and Engineering،Vol. 2017, no. 2017, pp.1-6.
https://search.emarefa.net/detail/BIM-1123844
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
Ko, Il-Ju…[et al.]. Ionothermal Synthesis of a Novel 3D Cobalt Coordination Polymer with a Uniquely Reported Framework: [BMI]2[Co2(BTC)2(H2O)2]. Advances in Materials Science and Engineering No. 2017 (2017), pp.1-6.
https://search.emarefa.net/detail/BIM-1123844
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
Ko, Il-Ju& Oh, Hyun-Chang& Cha, Yong-Jun& Han, Chae Hyeok& Choi, Eun-Young. Ionothermal Synthesis of a Novel 3D Cobalt Coordination Polymer with a Uniquely Reported Framework: [BMI]2[Co2(BTC)2(H2O)2]. Advances in Materials Science and Engineering. 2017. Vol. 2017, no. 2017, pp.1-6.
https://search.emarefa.net/detail/BIM-1123844
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes bibliographical references
رقم السجل
BIM-1123844
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
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