Synthesis and crystal structure of mercury complex of saccharin with pyridine [Hg(sac)‎2(py)‎2]

الملخص EN

The structure of the mercury saccharinate complex with pyridine has been studied by IR and single crystal X-ray diffraction methods.

The compound was crystallized in the monoclinic space group P21/n with unit cell dimensions of a = 9.8114(2), b = 21.2444(3), c = 12.0557(5), β = 97.8431(8)o , Z = 4, and the crystal structure was solved to an R value of 0.0425 for 5700 observations.

The Hg atom has slightly distorted tetrahedral configuration with four nitrogen (N) atoms from two pyridine and two saccharinate anions in the complex.