Synthesis and crystal structure of mercury complex of saccharin with pyridine [Hg(sac)2(py)2]
Joint Authors
Seddigi, Zaki S.
Banu, Afroza
Husayn, G. M. Golzar
Source
The Arabian Journal for Science and Engineering. Section A, Science
Issue
Vol. 32, Issue 2A (31 Jul. 2007), pp.181-187, 7 p.
Publisher
King Fahd University of Petroleum and Minerals
Publication Date
2007-07-31
Country of Publication
Saudi Arabia
No. of Pages
7
Main Subjects
Topics
Abstract AR
تمت – في هذا البحث – دراسة التركيب لمعقد الزئبق و الساكرنايت مع البيريدين باستخدام طريقة حيود الأشعة السينية للبلورة المفردة و دراسة أطياف الأشعة تحت الحمراء.
و قد وجدنا أن المعقد تمت بلورته في المجموعة الفراغية أحادية الميل بوحدة خلية ذات الأبعاد a = 9.8114(2)، 21.2444(3) = b، 12.557(5) = c انغستروم، و زواية بيتا = 97.8431 (8)˚ درجة.
و عدد جزئيات المعقد في وحدة الخلية يساوي أربع جزئيات.
و قد تم كذلك إيجاد حلول التركيب البلوري للمعقد باستخدام العديد من البرامج الحسابية حيث كان دليل R لعدد 5700 من الانعكاسات المجمعة 0.0425 =.
Abstract EN
The structure of the mercury saccharinate complex with pyridine has been studied by IR and single crystal X-ray diffraction methods.
The compound was crystallized in the monoclinic space group P21/n with unit cell dimensions of a = 9.8114(2), b = 21.2444(3), c = 12.0557(5), β = 97.8431(8)o , Z = 4, and the crystal structure was solved to an R value of 0.0425 for 5700 observations.
The Hg atom has slightly distorted tetrahedral configuration with four nitrogen (N) atoms from two pyridine and two saccharinate anions in the complex.
American Psychological Association (APA)
Seddigi, Zaki S.& Banu, Afroza& Husayn, G. M. Golzar. 2007. Synthesis and crystal structure of mercury complex of saccharin with pyridine [Hg(sac)2(py)2]. The Arabian Journal for Science and Engineering. Section A, Science،Vol. 32, no. 2A, pp.181-187.
https://search.emarefa.net/detail/BIM-345498
Modern Language Association (MLA)
Husayn, G. M. Golzar…[et al.]. Synthesis and crystal structure of mercury complex of saccharin with pyridine [Hg(sac)2(py)2]. The Arabian Journal for Science and Engineering. Section A, Science Vol. 32, no. 2A (Jul. 2007), pp.181-187.
https://search.emarefa.net/detail/BIM-345498
American Medical Association (AMA)
Seddigi, Zaki S.& Banu, Afroza& Husayn, G. M. Golzar. Synthesis and crystal structure of mercury complex of saccharin with pyridine [Hg(sac)2(py)2]. The Arabian Journal for Science and Engineering. Section A, Science. 2007. Vol. 32, no. 2A, pp.181-187.
https://search.emarefa.net/detail/BIM-345498
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 186-187
Record ID
BIM-345498
