Electron transfer at semiconductor liquid interfaces

الملخص EN

Electron Transfer reaction rate constants at Semiconductor / Liquid interfaces are calculated dy using the Fermi Golden Rule for Semiconductor.

The reorganization energy eV is computed for Semiconductor / Liquid Interfaces system in two solvents and compared with experimental value.

The driving force (free energy) ΔGo(eV) is calculated depending on spectrum Ru(H2L`)2 (NCS)2 .

The transfer is treated according with weak coupling (nonadiabatic) for two – state level between the Semiconductor and acceptor molecule state.