Photooxygenations and Self-Sensitizations of Naphthylamines: Efficient Access to Iminoquinones

Abstract EN

A series of spiro [fluorene-9,7′-dibenzo[c,h]acridine]-5′-one (SFDBAO) derivatives have been concisely and cleanly obtained by exposure to sunlight without external photosensitizers in the higher yields than that when using a UV lamp.

An interesting autocatalyst and self-sensitive procedure have been proposed to explain the effective photooxygenation.

SFDBAO derivatives exhibit the continuous π-stacks in single-crystal and electron-withdraw properties with red light-emitting and photovoltaic properties.