Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure
Joint Authors
Shi, Jing
Zhang, Fumin
Zhong, Yijun
Liu, Huanhuan
Fu, Yanghe
Hei, Shengtao
Zhu, Weidong
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-4, 4 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-10-03
Country of Publication
Egypt
No. of Pages
4
Main Subjects
Abstract EN
MIL-100(Fe), a mesoporous metal-organic framework (MOF), has a large BET specific surface area and pore volume with the presence of a significant amount of accessible Lewis acid metal sites upon dehydration.
The structural characteristics of MIL-100(Fe) make it a good candidate for potential applications in gas storage, separation, and heterogeneous catalysis.
Mainly, this MOF is obtained by the hydrothermal synthesis in a Teflon-lined autoclave at high temperature (>150°C) under static conditions.
However, this method has several disadvantages such as high temperature, high (autogenous) pressure, long time, and comparable low MOF yield.
Therefore, development of a facile method for synthesis of MIL-100(Fe) is vitally important for fundamental understanding and practical application.
Herein, MIL-100(Fe) is synthesized by a facile low-temperature (<100°C) synthesis route at atmospheric pressure by reaction of metallic iron and trimesic acid in water.
Due to our synthesis is conducted with agitation, higher MOF yield (>90%) still could be achieved, suggesting that this simple and energy saving method has the potential to be used practically.
American Psychological Association (APA)
Shi, Jing& Hei, Shengtao& Liu, Huanhuan& Fu, Yanghe& Zhang, Fumin& Zhong, Yijun…[et al.]. 2013. Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure. Journal of Chemistry،Vol. 2013, no. 2013, pp.1-4.
https://search.emarefa.net/detail/BIM-498519
Modern Language Association (MLA)
Shi, Jing…[et al.]. Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure. Journal of Chemistry No. 2013 (2013), pp.1-4.
https://search.emarefa.net/detail/BIM-498519
American Medical Association (AMA)
Shi, Jing& Hei, Shengtao& Liu, Huanhuan& Fu, Yanghe& Zhang, Fumin& Zhong, Yijun…[et al.]. Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure. Journal of Chemistry. 2013. Vol. 2013, no. 2013, pp.1-4.
https://search.emarefa.net/detail/BIM-498519
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-498519