Retrogradation of Waxy Rice Starch Gel in the Vicinity of the Glass Transition Temperature

Abstract EN

The retrogradation rate of waxy rice starch gel was investigated during storage at temperatures in the vicinity of the glass transition temperature of a maximally concentrated system (Tg′), as it was hypothesized that such temperatures might cause different effects on retrogradation.

The Tg′ value of fully gelatinized waxy rice starch gel with 50% water content and the enthalpy of melting retrograded amylopectin in the gels were investigated using differential scanning calorimetry.

Starch gels were frozen to −30°C and stored at 4, 0, −3, −5, and −8°C for 5 days.

The results indicated that the Tg′ value of gelatinized starch gel annealed at −7°C for 15 min was −3.5°C.

Waxy rice starch gels retrograded significantly when stored at 4°C with a decrease in the enthalpy of melting retrograded starch in samples stored for 5 days at −3, −5, and −8°C, respectively, perhaps due to the more rigid glass matrix and less molecular mobility facilitating starch chain recrystallization at temperatures below Tg′.

This suggests that retardation of retrogradation of waxy rice starch gel can be achieved at temperature below Tg′.